Enhanced co-formed/meltblown fibrous web structure

ABSTRACT

An enhanced, co-formed fibrous web structure is disclosed. The web structure may have a co-formed core layer sandwiched between two scrim layers. The core layer may be formed of a blend of cellulose pulp fibers and melt spun filaments. The scrim layers may be formed of melt spun filaments. Filaments of one or both of the scrim layers, and optionally the core layer, may also be meltblown filaments. The fibrous web structure may have a Consumer Preference Indication (governing allocation of melt spun filaments between core layer and scrim layers) greater than 0. Alternatively, the filaments forming the scrim layers may constitute from 1 to 13 percent of the weight of the structure. Alternatively, the scrim layers may have a combined basis weight of from 0.1 gsm to less than 3.0 gsm. A method for forming the structure, including direct formation of layers, is also disclosed.

CROSS REFERENCE TO RELATED APPLICATION

This application claims the benefit of U.S. Provisional Application No.62/186,465, filed Jun. 30, 2015, the substance of which is incorporatedherein by reference.

BACKGROUND OF THE INVENTION

Wet wipes cut from fibrous web structures formed in a co-forming processhave been marketed for several years. The co-forming process involvesmelt spinning continuous filaments from polymer resin, andsimultaneously, directing an air stream with entrained distributedcellulose fibers together with the filaments, typically into aco-forming box or similar blending apparatus, blending the filaments andfibers, and directing the blend along to a collecting/forming structuresuch as a moving forming belt. The filaments may be spun and introducedinto the airstream carrying the cellulose fibers, or an airstreamcarrying the cellulose fibers may be introduced into the pathway of thefilaments following spinning, the effect being the deposit of anentangled blend of filaments and fibers onto the moving formingstructure and accumulation and formation of a batt thereof. Uponsubsequent consolidation and bonding of the batt, a cohesive fibrous webstructure may be formed. The co-forming process is, advantageously,typically dry, in contrast to wet forming techniques often used to makeproducts such as paper towels from cellulose pulp. The co-formed fibrousweb structure may be used, for example, as a wet wipe substrate. Theentangled polymer filaments in the co-formed structure provide a matrixthat holds the relatively short fibers, entangled therewithin, in placewithin the structure, and thereby help maintain structural integrity ofthe structure when it is wetted with an aqueous lotion.

The fibrous web structure from which wet wipes (for example, baby wipes)are made, should be strong enough when moistened with a lotion tomaintain structural integrity in use, but also soft enough to give apleasing and comfortable tactile sensation to the user. In addition, thestructure should have suitable absorbency, porosity and surface textureto be effective in absorbing, retaining and carrying an aqueous lotion,releasing the lotion under pressure during use, and in cleaning soiledskin, while at the same time providing a reliable barrier between theuser's hand and the soil (e.g., fecal matter).

In addition, cost and environmental sustainability concerns imposepressure to further improve the performance of wipes to enable bettercleaning with less material, without compromising lotion carrying andrelease and other important properties such as tensile strength andprotection.

Recently, improvements have been introduced to the co-forming processand resulting fibrous web structure. As described in U.S. applicationSer. No. 13/076,492, a co-formed fibrous web structure with improvedabsorption properties is described.

In addition to the other improvements described in that application, itis briefly surmised that layers formed of meltblown polymer filamentsalone can be formed on the outermost surfaces of the co-formed battprior to bonding, to beneficial effect. It is surmised that the additionof the meltblown layer (called “scrim”) can help reduce release of lint(comprising fibers dislodged from the structure) during use by aconsumer.

However, the ways in which inclusion of scrim layers, and the relativeproportions of components of the scrim layers and intermediate or corelayers, affect properties such as tensile strength, drape, surfacefriction, opacity, texture and feel of the web material, have not beenapparent or predictable. Thus, it would be beneficial if the bestproportions of components overall, together with their allocations amongthe various layers or substructures, of a fibrous web structure havingscrim layers, and any other improvements making the structure desirablefor use as wet wipe substrate, could be identified.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a schematic perspective illustration of an example of afibrous web structure.

FIG. 2 is a schematic, cross-sectional representation of FIG. 1 takenalong line 4-4;

FIG. 3 is a scanning electron microscope image of a cross-section of anexample of fibrous web structure.

FIG. 4 is a schematic, perspective illustration of an example of afibrous web structure.

FIG. 5 is a schematic, cross-sectional representation of an example of afibrous web structure.

FIG. 6A is a schematic, cross-sectional illustration of an example of afibrous web structure.

FIG. 6B is a scanning electron microscope image of a plan view of anexample of scrim formed of meltblown filaments (overlying an unrelatedsupporting surface).

FIG. 6C is a scanning electron microscope image of cross-section of anexample of a fibrous web structure depicting outer scrim layers formedof meltblown filaments sandwiching a core layer formed of a blend ofpulp fibers and meltblown filaments.

FIG. 6D is a scanning electron microscope image of cross-section of anexample of a fibrous web structure depicting outer scrim layers formedof meltblown filaments sandwiching a core layer formed of a blend ofpulp fibers and meltblown filaments, proximate a thermal bond.

FIG. 7A is a schematic illustration of an example of a system andprocess for making a fibrous web structure.

FIG. 7B is a schematic illustration of another example of a system andprocess for making a fibrous web structure.

FIG. 8 is a schematic illustration of an example of a patterned belt foruse in a process.

FIG. 9A is a schematic perspective-view illustration of a portion of anexample of a spinneret with a plurality of nozzles and attenuation fluidoutlets.

FIG. 9B is a schematic end-view illustration of an example of a nozzlein a spinneret with a melt exit hole and an attenuation fluid outletuseful in spinning filaments.

FIG. 10 is an example of a thermal bond pattern that can be imparted toa fibrous web structure.

FIG. 11 is a schematic illustration of an example of a stack of wetwipes in a tub.

FIG. 12 is a ternary plot of the fraction of pulp, the fraction ofmeltblown polypropylene filaments present in two scrim layers, and thefraction of meltblown polypropylene filaments in the core layer, of thetotal weight, of each of seventeen samples of fibrous web structurescomprising pulp fibers and meltblown polypropylene filaments.

FIG. 13 is an enlarged view of the portion of the plot of FIG. 12occupied by data points.

FIG. 14A is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting wet cross direction peak tensilestrength according to the fraction of pulp fibers, the fraction ofmeltblown polypropylene filaments in scrim layers, and the fraction ofmeltblown polypropylene filaments in a core layer, of a fibrous webstructure.

FIG. 14B is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting wet machine direction peak tensilestrength according to the fraction of pulp fibers, the fraction ofmeltblown polypropylene filaments in scrim layers, and the fraction ofmeltblown polypropylene filaments in a core layer, of a fibrous webstructure.

FIG. 14C is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting wet opacity according to the fractionof pulp fibers, the fraction of meltblown polypropylene filaments inscrim layers, and the fraction of meltblown polypropylene filaments in acore layer, of a fibrous web structure with a basis weight of 55 gsm.

FIG. 14D is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting wet opacity according to the fractionof pulp fibers, the fraction of meltblown polypropylene filaments inscrim layers, and the fraction of meltblown polypropylene filaments in acore layer, of a fibrous web structure with a basis weight of 60 gsm.

FIG. 14E is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting perceived flexibility (wet) accordingto the fraction of pulp fibers, the fraction of meltblown polypropylenefilaments in scrim layers, and the fraction of meltblown polypropylenefilaments in a core layer, of a fibrous web structure having a basisweight of 55 gsm.

FIG. 14F is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting perceived flexibility (wet) accordingto the fraction of pulp fibers, the fraction of meltblown polypropylenefilaments in scrim layers, and the fraction of meltblown polypropylenefilaments in a core layer, of a fibrous web structure having a basisweight of 60 gsm.

FIG. 14G is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting perceived surface roughness (wet)according to the fraction of pulp fibers, the fraction of meltblownpolypropylene filaments in scrim layers, and the fraction of meltblownpolypropylene filaments in a core layer, of a fibrous web structure.

FIG. 14H is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting Consumer Preference Indication (CPI)(wet) according to the fraction of pulp fibers, the fraction ofmeltblown polypropylene filaments in scrim layers, and the fraction ofmeltblown polypropylene filaments in a core layer, of a fibrous webstructure having a basis weight of 55 gsm.

FIG. 14I is a view of the portion of the plot shown in FIG. 13, overlaidwith shaded bands reflecting application of a predictive model developedfrom the data points, predicting Consumer Preference Indication (CPI)(wet) according to the fraction of pulp fibers, the fraction ofmeltblown polypropylene filaments in scrim layers, and the fraction ofmeltblown polypropylene filaments in a core layer, of a fibrous webstructure having a basis weight of 60 gsm.

DETAILED DESCRIPTION OF EMBODIMENTS

Definitions

As used herein, the articles “a” and “an” when used herein, for example,“an anionic surfactant” or “a fiber” is understood to mean one or moreof the material that is claimed or described.

“Basis Weight” is the weight per unit surface area (in amachine-direction/cross-direction plane) of a sample of web material (onone side), expressed in grams/meter2 (gsm). Basis weight may bespecified in manufacturing specifications, and also may be measured, andreflects the weight of the material prior to addition of any liquidcomposition.

“Co-formed fibrous web structure” as used herein means that the fibrousweb structure comprises an intermixed and/or entangled blend of at leasttwo different materials wherein at least one of the materials comprisesfilaments, such as spun polymer filament (e.g., filaments spun frompolypropylene resin), and at least one other material, different fromthe first material, comprises fibers. In one example, a co-formedfibrous web structure comprises fibers, such as cellulose or wood pulpfibers, and filaments, such as spun polypropylene filaments. A co-formedfibrous web structure may also comprise solid particulate additives suchas but not limited to absorbent gel materials, filler particles,particulate spot bonding powders or clays.

“Cross Direction” or “CD” with respect to a fibrous web structure meansthe direction perpendicular to the predominant direction of movement ofthe fibrous web structure through its manufacturing line.

“Fiber” means an elongate particulate having a limited length exceedingits width or diameter, i.e. a length to width ratio of no more than 200.For purposes of the present disclosure, a “fiber” is an elongateparticulate as described above that has a length of less than 3 cm.Fibers are typically considered discontinuous in nature. Non-limitingexamples of fibers include hardwood and softwood pulp fibers; hemp bast;bagasse; bamboo; corn stalk; cotton; cotton stalk; cotton linters;esparto grass; flax tow; jute bast; kenaf bast; reed; rice straw, sisal;switch grass; wheat straw; and synthetic staple (i.e., cut or chopped)spun fibers made from polyester, nylons, rayon (including viscose andlyocell); polyolefins such as polypropylene and polyethylene, naturalpolymers, such as starch, starch derivatives, cellulose and cellulosederivatives, hemicellulose, hemicellulose derivatives, chitin, chitosan,polyisoprene (cis and trans), peptides, polyhydroxyalkanoates,copolymers of polyolefins such as polyethylene-octene, and biodegradableor compostable thermoplastics such as polylactic acid, polyvinylalcohol, and polycaprolactone. Synthetic fibers may be monocomponent ormulticomponent, e.g., bicomponent. For purposes herein, “long fibers”have an average length exceeding 10 mm; “medium length fibers” have anaverage length of from 2 mm and 10 mm; and “short fibers” have anaverage length less than 2 mm.

“Fibrous web structure” as used herein means a web or sheet structureformed of one or more types of filaments and/or fibers. The term“fibrous web structure” encompasses nonwovens.

A “filament” is an elongate particulate having a theoretically unlimitedlength, but at least a length-to-width and/or length-to-diameter ratiogreater than 500 and a length greater than 5.08 cm. Filaments aretypically spun in a continuous process, and are, therefore, consideredsubstantially “continuous” in nature, having an indeterminate length.Non-limiting examples of filaments include meltspun/meltblown orspunbond filaments spun from polymer resin. Non-limiting examples ofmaterials that can be spun into filaments include natural polymers, suchas starch, starch derivatives, cellulose and cellulose derivatives,hemicellulose, hemicellulose derivatives, chitin, chitosan, polyisoprene(cis and trans), peptides, polyhydroxyalkanoates, and synthetic polymersincluding, but not limited to, thermoplastic polymers, such aspolyesters, nylons, polyolefins such as polypropylene, polyethylene,polyvinyl alcohol and polyvinyl alcohol derivatives, sodium polyacrylate(absorbent gel material), and copolymers of polyolefins such aspolyethylene-octene, and biodegradable or compostable thermoplasticfibers such as polylactic acid, polyvinyl alcohol, and polycaprolactone.Filaments may be monocomponent or multicomponent, e.g., bicomponent.

“Like chemistry,” with respect to two polymers, two blends of polymers,or a polymer and a blend of polymers, means that the two polymers, twoblends of polymers, or a polymer and a blend of polymers, are capable ofmixing at a temperature of 250° C. or lower, to form a singlethermodynamic phase.

“Liquid composition” refers to any liquid, including, but not limited toa pure liquid such as water, an aqueous solution, a colloid, an emulsion(including oil-in-water and water-in-oil), a suspension, a solution andmixtures thereof. The term “aqueous solution” as used herein, refers toa solution that is at least about 20%, at least about 40%, or even atleast about 50% water by weight, and is no more than about 95%, or nomore than about 90% water by weight. The term “liquid composition”encompasses a lotion or other cleaning or skin conditioning formulationthat may be included with wet wipes.

“Machine Direction” or “MD” with respect to a fibrous web structuremeans the direction parallel to the predominant direction of movement ofthe fibrous web structure through its manufacturing line.

“Meltblown” and forms thereof refer to a process of making filaments andwebs thereof, in which filaments are spun by extruding streams of moltenpolymer resin under pressure through one or more spinnerets, and thensubstantially attenuating (elongating and reducing diameter and/or widthof) the polymer streams following their exit from the spinnerets, withone or more high-velocity streams of heated air proximate the exits ofthe spinnerets. The air handling equipment (such as a manifold) may be aseparate or integral part of the spinneret and is configured to directthe air stream(s) along path(s) at least partially parallel to thedirection of extrusion of the polymer streams. Meltblown filaments aredistinguished from polymer filaments made by other spunbond ormelt-spinning processes by their comparatively very small diameterand/or very small width, imparted by the attenuating air streams, andtypically have an average diameter or width of from 0.1 μm to 30 μm, 15μm, 10 μm or even 5 μm. Following attenuation, the filaments may be airquenched with cooling air, or mist quenched with a mixture of coolingair and water droplets. The spun, attenuated and quenched fibers arethen typically directed toward and accumulated in somewhat random,varying and entangled orientation on, a moving belt or rotating drum, toform a web.

“Nonwoven” for purposes herein means a consolidated web of fibers,continuous filaments, or chopped or staple fibers of any nature ororigin, or any blend thereof, which have been formed into a web, andbonded together by any means, with the exception of weaving or knitting.A nonwoven is an example of a fibrous web structure. “Nonwoven” does notinclude nonfibrous skin-like or membrane-like materials with acontinuous structure sometimes identified or described as “films”.“Nonwoven” does not include a product, such as paper, in which cellulosepulp fibers are distributed via a wetlaying process to form a sheet orweb, without the need for any post-formation bonding processes tocomplete formation of the sheet or web.

“Particulate” as used herein means a granular substance or powder.

“Predominate” or a form thereof, with respect to a proportion of acomponent of a structure or composition, means that the componentconstitutes the majority of the weight of the structure or composition.

“Pre-moistened” and “wet” are used interchangeably herein and refer tofibrous web structures and/or wipes which are moistened with a liquidcomposition prior to packaging, and may be packaged in an effectivelymoisture impervious container or wrapper. Such pre-moistened wipes,which can also be referred to as “wet wipes,” may be suitable for usefor cleaning a baby's skin (such, as, e.g., during a diaper change), aswell the skin of older children and adults.

“Stack” refers to an orderly pile of individually cut portions offibrous web structure, e.g., wipes. Based upon the assumption that thereare at least three wipes in a stack, each wipe, except for the topmostand bottommost wipes in the stack, will be in direct contact with thewipe directly above and below itself in the stack. Moreover, when viewedfrom above, the wipes will be layered on top of each other, orsuperimposed, such that only the topmost wipe of the stack will bevisible. The height of the stack is measured from the bottom of thebottommost wipe in the stack to the top of the topmost wipe in the stackand is provided in units of millimeters (mm).

“Surfactant” as used herein, refers to materials which preferably orienttoward an interface. Surfactants include the various surfactants knownin the art, including: nonionic surfactants; anionic surfactants;cationic surfactants; amphoteric surfactants, zwitterionic surfactants;and mixtures thereof.

Herein, where the quantity of a component of a fibrous web structure isexpressed in “X weight percent” or “X percent by weight,” or anabbreviated or shortened form thereof, the quantity means that thecomponent's weight constitutes X percent of the total weight of thefibrous web structure.

“z-direction” with respect to a web or a fibrous web structure means thedirection orthogonal to the plane defined by the machine direction andcross direction of the web or fibrous web structure.

Unless otherwise noted, all component or composition levels are inreference to the active level of that component or composition, and areexclusive of impurities, for example, residual solvents or by-products,which may be present in commercially available sources.

Fibrous Web Structure

A fibrous web structure within the scope of the present invention mayhave a basis weight between about 10 gsm to about 120 gsm and/or fromabout 20 gsm to about 110 gsm and/or from about 30 gsm to about 100 gsmand/or from about 40 to 90 gsm. For purposes of use for making babywipes, from product testing and consumer research it is believed that afibrous web structure as disclosed herein having a basis weight from 40gsm to 90 gsm and more preferably from 45 gsm to 85 gsm strikes the bestbalance between thickness/caliper, absorption capacity, opacity, drapeand feel, and tensile strength, on one hand, and economy, on the otherhand.

The fibrous web structure may include additives such as softeningagents, temporary wet strength agents, permanent wet strength agents,bulk softening agents, silicones, wetting agents, latexes, especiallysurface-pattern-applied latexes, dry strength agents such ascarboxymethylcellulose and starch, and other types of additives suitablefor inclusion in and/or on fibrous web structures.

Fibrous web structures with the scope of the present invention may beformed of a plurality of filaments, a plurality of fibers, and a mixtureof filaments and fibers.

FIGS. 1 and 2 show schematic representations of an example of a fibrousweb structure.

Fibers useful as components of the fibrous web structure includecellulosic fibers commonly known as wood pulp fibers. Applicable woodpulps include chemical pulps, such as Kraft, sulfite, and sulfate pulps,as well as mechanical pulps including, for example, groundwood,thermomechanical pulp and chemically modified thermomechanical pulp.Chemical pulps, however, may be preferred since they impart a superiortactile sense of softness to tissue sheets made therefrom. Pulps derivedfrom both angiosperm (flowering) trees (hereinafter, also referred to as“hardwood”) and gymnosperm (coniferous) trees (hereinafter, alsoreferred to as “softwood”) may be utilized. The hardwood and softwoodfibers can be blended, or alternatively, can be deposited in layers toprovide a stratified web. U.S. Pat. No. 4,300,981 and U.S. Pat. No.3,994,771 are incorporated herein by reference for the purpose ofdisclosing layering of hardwood and softwood fibers. Also applicable arefibers derived from recycled paper, which may contain any or all of theabove categories as well as other non-fibrous materials such as fillersand adhesives used to facilitate the original papermaking.

A blend of long, or medium-length, pulp fibers, and short pulp fibersmay be suitable for purposes herein. Generally, long and medium-lengthfibers tend to be larger and more coarse, providing desirable textureand absorption characteristics, while short fibers tend to be finer andsofter, enhancing opacity of the structure and adding tactile softness.Including short pulp fibers as a portion of the fiber blend may bebeneficial for controllably including consolidated masses of fibers inthe blend.

In one example, a blend of softwood pulp fibers (medium-length) andhardwood pulp fibers (short) may be used. The softwood and hardwood pulpfibers, or medium-length and short fibers, may be included in a weightratio of 20:80 to 90:10. For purposes herein, it may be desired that theweight ratio of softwood fibers to hardwood fibers, or weight ratio ofmedium-length fibers to short fibers, be from 60:40 to 90:10, morepreferably 65:35 to 85:15, and still more preferably 70:30 to 80:20 inthe structure. In a more particular example within these ranges, thesoftwood pulp fibers may be SSK (southern softwood kraft) pulp fibers.In another more particular example within these ranges, the hardwoodpulp fibers may be birch, aspen or eucalyptus pulp fibers. In a stillmore particular example within these ranges, the softwood pulp fibersmay be SSK pulp fibers and the hardwood pulp fibers may be birch, aspenor eucalyptus and softness, which contribute to enhancing opacity andsoftness of the fibrous web structure, and eucalyptus pulp may beparticularly preferred for these characteristics.

In addition to the various wood pulp fibers, other cellulosic fiberssuch as cotton linters, rayon, lyocell, viscose and bagasse may be used.Other sources of cellulose in the form of fibers or materials capable ofbeing spun into fibers include grasses and grain sources.

As shown in FIGS. 1 and 2, the fibrous web structure 10 may be aco-formed fibrous web structure. The fibrous web structure 10 comprisesa plurality of filaments 12, such as polypropylene filaments, and aplurality of fibers, such as wood pulp fibers 14. The filaments 12 maybe randomly arranged as a result of the process by which they are spunand/or formed into the fibrous web structure 10. The wood pulp fibers14, may be randomly dispersed throughout the fibrous web structure 10 inthe x-y (machine-direction/cross-direction) plane. The wood pulp fibers14 may be non-randomly dispersed throughout the fibrous web structure inthe z-direction. In one example (not shown), the wood pulp fibers 14 arepresent at a higher concentration on one or more of the exterior, x-yplane surfaces than within the fibrous web structure along thez-direction.

FIG. 3 shows a cross-sectional, scanning electron microscope image of anexample of a fibrous web structure 10 a including a non-random,repeating pattern of microregions 15 a and 15 b. The microregion 15 a(typically referred to as a “pillow”) exhibits a different value of alocalized property than microregion 15 b (typically referred to as a“knuckle”). In one example, the microregion 15 b is a continuous orsemi-continuous network and the microregion 15 a are discrete regionswithin the continuous or semi-continuous network. The localized propertymay be caliper. In another example, the localized property may bedensity.

As shown in FIG. 4, another example of a fibrous web structure is alayered fibrous web structure 10 b. The layered fibrous web structure 10b includes a first layer 16 comprising a plurality of filaments 12, suchas polypropylene filaments, and a plurality of fibers, in this example,wood pulp fibers 14. The layered fibrous web structure 10 b furthercomprises a second layer 18 comprising a plurality of filaments 20, suchas polypropylene filaments. In one example, the first and second layers16, 18, respectively, are sharply defined zones of concentration of thefilaments and/or fibers. The plurality of filaments 20 may be depositeddirectly onto a surface of the first layer 16 to form a layered fibrousweb structure that comprises the first and second layers 16, 18,respectively.

Further, the layered fibrous web structure 10 b may comprise a thirdlayer 22, as shown in FIG. 4. The third layer 22 may comprise aplurality of filaments 24, which may be the same or different from thefilaments 20 and/or 16 in the second 18 and/or first 16 layers. As aresult of the addition of the third layer 22, the first layer 16 ispositioned, for example sandwiched, between the second layer 18 and thethird layer 22. The plurality of filaments 24 may be deposited directlyonto a surface of the first layer 16, opposite from the second layer, toform the layered fibrous web structure 10 b that comprises the first,second and third layers 16, 18, 22, respectively.

FIG. 5 is a cross-sectional schematic illustration of another example ofa fibrous web structure comprising a layered fibrous web structure 10 c.The layered fibrous web structure 10 c includes a first layer 26, asecond layer 28 and optionally a third layer 30. The first layer 26 maycomprise a plurality of filaments 12, such as polypropylene filaments,and a plurality of fibers, such as wood pulp fibers 14. The second layer28 may comprise any suitable filaments, fibers and/or polymeric films.In one example, the second layer 28 comprises a plurality of filaments34. In one example, the filaments 34 comprise a polymer selected fromthe group consisting of: polysaccharides, polysaccharide derivatives,polyvinylalcohol, polyvinylalcohol derivatives and mixtures thereof.

In yet another example, a fibrous web structure may include two outerlayers consisting of 100% by weight filaments and an inner layerconsisting of 100% by weight fibers.

In another example, instead of being layers of fibrous web structure 10c, the material forming layers 26, 28 and 30, may be in the form oflayers wherein two or more of the layers may be combined to form afibrous web structure. The layers may be bonded together, such as bythermal bonding and/or adhesive bonding, to form a multi-layer fibrousweb structure.

Another example of a fibrous web structure is schematically illustratedin FIG. 6A. The fibrous web structure 10 d may comprise two or morelayers, wherein one layer 36 comprises any suitable fibrous webstructure in accordance with the present disclosure, for example fibrousweb structure 10 as shown in FIGS. 1 and 2 and another layer 38comprising any suitable fibrous web structure, for example a fibrous webstructure comprising filaments 12, such as polypropylene filaments. Thefibrous web structure of layer 38 may be in the form of a net, mesh,scrim or other structure that includes pores that expose one or moreportions of the fibrous web structure 10 d to an external environmentand/or at least to liquids that may come into contact, at leastinitially, with the fibrous web structure of layer 38. In one example,layer 38 may be a layer of scrim formed of a deposit of somewhat, orsubstantially, randomly laid and/or accumulated meltblown polymerfilaments.

In addition to layer 38, the fibrous web structure 10 d may furthercomprise layer 40. Layer 40 may comprise a fibrous web structurecomprising filaments 12, such as polypropylene filaments, and may be thesame or different from the fibrous web structure of layer 38.

Two or more of the layers 36, 38 and 40 may be bonded together, such asby thermal bonding and/or adhesive bonding, to form a multi-layerfibrous web structure. After a bonding operation, especially a thermalbonding operation, it may be difficult to distinguish the layers of thefibrous web structure 10 d and the fibrous web structure 10 d mayvisually and/or physically be similar to a layered fibrous web structurein that one would have difficulty separating the once individual layersfrom each other. In one example, layer 36 may comprise a fibrous webstructure that exhibits a basis weight of at least about 15 gsm and/orat least about 20 gsm and/or at least about 25 gsm and/or at least about30 gsm up to about 120 gsm and/or 100 gsm and/or 80 gsm and/or 60 gsmand the layers 38 and 42, when present, independently and individually,may comprise fibrous web structures that exhibit basis weights of lessthan about 10 gsm and/or less than about 7 gsm and/or less than about 5gsm and/or less than about 3 gsm and/or less than about 2.5 gsm, or fromgreater than 0 gsm to less than about 2.5 gsm, or from 0.5 gsm to 2.5gsm.

Layers 38 and 40, when present, may help retain the fibers, in this casethe wood pulp fibers 14, on and/or within the fibrous web structure oflayer 36 thus reducing lint and/or dust (as compared to a single-layerfibrous web structure comprising the fibrous web structure of layer 36without the layers 38 and 40) resulting from the wood pulp fibers 14becoming free from the fibrous web structure of layer 36.

FIG. 6B is a scanning electron microscope image of a plan view of anexample of scrim layer (overlying an unrelated supporting surface) thatmay be formed in a meltblowing process, creating a network ofsubstantially randomly-laid, continuous fine filaments. The thicknessand basis weight of the layer may be controlled by controlling the rateof throughput of polymer resin through the meltblowing equipment, andthe rate of speed of the collecting belt, drum or other surface uponwhich the filaments are collected after spinning. In FIG. 6B it can beseen that the filaments create a highly porous network of finefilaments.

FIGS. 6C and 6D are scanning electron microscope images ofcross-sections of examples of a fibrous web structure depicting outerscrim layers 38, 40 formed of meltblown fibers, sandwiching a core layer36 formed of a blend of pulp fibers and meltblown filaments. In FIGS. 6Cand 6D it can be seen that the continuous filaments of the scrim layers38, 40 are substantially finer than the pulp fibers in the core layer36. When built up to a suitable basis weight, and in combination with apattern of thermal bonds 70 binding the structure together in thez-direction, the scrim layers serve to help contain the relativelyshorter and coarser pulp fibers within the structure. For themanufacturer, this desirably reduces release of pulp fibers into theplant environment in downstream processes involving the fibrous nonwovenstructure, reducing contamination of equipment, among other benefits.For the consumer of a product made from the fibrous nonwoven structure,this desirably increases abrasion resistance of the product and reducesshedding of pulp fibers (“linting”) from rubbing friction of the productduring its use. Additionally, as has been found, surprisingly, inclusionof scrim layers imparts added tensile strength to the fibrous webstructure, even when it constitutes a mere reallocation of a portion ofthe meltblown filaments from the core layer. Added tensile strengthreduces incidents of tearing and puncturing of the structure,benefitting both the manufacturer in downstream processing, and theconsumer in use of a product made from the structure.

It should also be noted that the presence of polymer filaments in thecore layer 36 together with the presence of polymer filaments of likechemistry in the two outer scrim layers, facilitate formation of athermal bond 70 at which the polymer material in the three layers can bebrought together under heat and compression so that they at leastpartially fuse, as may be observed in FIG. 6D, thereby forming a robustbond through the web structure in the z-direction and holding the scrimlayers to the structure. This helps maintain consolidation of theaccumulated fibers and filaments, and enhances the structural integrityof the fibrous web structure. Further, it may be appreciated from FIG.6D that the presence of scrim layers on a fibrous nonwoven web structureenables creation of a clearly, sharply defined thermal bond, which mayenhance the visual appearance of thermal bond patterns that embody notonly functional, but esthetic aspects.

As noted, it is believed that inclusion of meltspun, in one examplemeltspun and meltblown, polymer filaments in a co-formed fibrous webstructure that is otherwise formed of cellulose or wood pulp fibers, asschematically illustrated in FIGS. 1 and 2 serves to enhance the tensilestrength and wet structural integrity of the structure, making itparticularly suitable for making wet wipes. Additionally, inclusion ofouter scrim layers formed of meltspun, in one example meltspun andmeltblown, polymer filaments as suggested and shown in FIGS. 6A-6Cserves to help contain the shorter and coarser pulp fibers within thestructure. Use of meltblown filaments to form outer scrim layers may bedesirable because the relatively fine meltblown fibers form a scrimstructure that is numerically dense (as compared to a structure ofsimilar basis weight but formed of meltspun but not meltblownfilaments), and therefore beneficial for containing fibers within thestructure.

However, adding polymer filaments to pulp fibers in a fibrous webstructure of a given basis weight (as occurs with the addition of outerscrim layers of meltblown polymer filaments) may compromise the capacityof the structure to absorb aqueous liquids, for many types of polymerstypically suitable and desirable for melt-spinning. This is due to thefact that, while pulp fibers are typically naturally hydrophilic, thepreferred polymer filaments, such as polypropylene filaments, aretypically naturally hydrophobic.

What remains to be decided, then, is an appropriate combination ofweight percent pulp fiber content vs. filament content, with anappropriate allocation of meltspun/meltblown filament content to thescrim layers.

For the liquid absorbency performance desired for a wet wipe product itmay be desired that the entire fibrous web structure be formed of atleast 50 percent, more preferably at least 60 percent, and still morepreferably at least 65 percent, by weight pulp fibers. Conversely, toachieve desired tensile strength and wet structural integrity, it may bedesired that the entire fibrous web structure include at least 10percent, at least 20 percent, or at least 25 percent, by weight polymerfilaments. Thus, in some examples it may be preferred that the fibrousweb structure be formed of 50 to 90 percent by weight pulp fibers, or 60to 85 percent by weight pulp fibers, or even 65 to 85 percent by weightpulp fiber. Correspondingly, in such examples the fibrous web structuremay comprise 10 to 50 percent by weight polymer filaments, or 15 to 40percent by weight polymer filaments, or even 15 to 35 percent by weightpolymer filaments, respectively.

Referring to FIGS. 6A-6D, what remains to be further decided is anappropriate allocation of polymer filaments between the inner or “core”layer(s) 36 and the outer scrim layers 38, 40 for purposes of bestmaximizing or appropriately balancing qualities such as drape orflexibility, surface roughness, tactile feel, opacity and tensilestrength. Within the contemplation of a structure as schematicallyillustrated in FIG. 6A, any quantity ranging from a very small portion,to nearly all, of the polymer filaments in the structure, may beallocated to the scrim layers. However, it was not expected or predictedthat, within the ranges of pulp and filament content set forth in thepreceding paragraph, reallocating a portion of polymer filaments fromthe inner core layer(s) to outer scrim layers of a fibrous web structurewould have any substantial effect on properties such as tensilestrength, opacity or flexibility of the structure, since it was believedthat a mere reallocation from core to scrim layers theoretically doesnot increase or decrease the number of filaments per unit surface areaof the structure.

In an attempt to determine appropriate combinations of pulp content andallocation of filaments between core and scrim layers, however,seventeen variants of a three layer (scrim-core-scrim) fibrous nonwovenweb structure such as schematically illustrated in FIG. 6A, of basisweights of about 55 gsm and 60 gsm, and comprising from about 65 percentto about 75 percent by weight SSK pulp fibers, and the remaindermeltblown polypropylene filaments, were manufactured. The two scrimlayers had approximately equal basis weights, for each variant. Thevariants had the weight fractions of SSK pulp fiber and allocations ofmeltblown polypropylene filaments reflected in the data points in theternary plot shown in FIGS. 12 and 13. (The values shown on the axes ofthe ternary plot of FIG. 12 may be converted to weight percentages bymultiplying them×100%) The weight fraction meltblown of polypropylenefilament content in a single outer scrim layer (i.e., on one side of thestructure) for any particular variant, is approximately the value shownin the ternary plot, divided by 2. (The three-axis “compass” appearingin FIG. 12 shows, respectively, the direction of increasing weightfraction of pulp fibers in the structure, the direction of increasingweight fraction of meltblown (MB) polymer filaments in the scrim layerscombined, and the direction of increasing weight fraction of meltblown(MB) polymer filaments in the core layer. This “compass” is alsoreproduced for reference in FIGS. 13 and 14A-14I.)

In a first assessment, wet cross direction and machine direction tensilestrength of these seventeen variants was measured and recorded. Aregression analysis was applied to the data and yielded a formula. Theformula predicts that adding meltblown polypropylene filaments to theoverall structure, enhances wet tensile strength. Surprisingly, however,the formula also predicts, generally, that increasing allocation of theadded filaments from the core layer to the scrim layers by even a smallamount appears to dramatically impact wet tensile strength of thefibrous nonwoven structure, with tensile strength increasing generallyas more filaments are allocated from the core layer to the scrimlayers—within the weight ratios of wood pulp fibers to polymer filamentscontemplated. This effect is illustrated in FIGS. 14A and 14B, in whichwet cross direction and machine direction peak tensile strength of thestructure is predicted to increase dramatically as the weight ratio ofmeltblown polymer filaments to pulp fibers is increased, and as theallocation of those meltblown polymer filaments is shifted from core toscrim layers. This is indicated by the shaded bands marked 141-144 inFIG. 14A, and shaded bands marked 145-148 in FIG. 14B.

Since this effect was not predicted, the reasons for it are notcurrently well understood. Without intending to be bound by theory, itis hypothesized that higher numeric density of meltblown filaments(i.e., greater consolidation in the z-direction) may contribute toadding tensile strength to a structure formed of the filaments, whilelower numeric density of meltblown filaments within the same space (suchas when separated in the z-direction by interspersed fibers) may reducetensile strength. Regardless, it was predicted that consumers ofproducts made from the structure, such as baby wipes, would prefercomparatively greater tensile strength in the structure. This is due tothe fact that comparatively greater tensile provides comparativelygreater resistance to tearing and puncturing in dispensation and use,and the fact that tearing or puncturing during dispensation and/or useare undesirable failures for a baby wipe. This prediction is alsosupported by results of consumer research, which suggest that consumerstend to prefer comparatively more strength and tear resistance in a babywipe.

In a second assessment, wet opacity of the seventeen variants wasmeasured and recorded. Another regression analysis was applied to thedata and yielded a formula. The formula predicted that opacity increasesas basis weight of the fibrous web structure is increased; compare FIGS.14C and 14D. This in itself was not surprising, since comparativelygreater basis weight equates with a comparatively greater number offibers and filaments per unit surface area, which would be expected tobe available to block or diffuse comparatively more light directedorthogonally at one surface. Surprisingly, however, the formula alsopredicts that opacity of the fibrous nonwoven structure generallyincreases as more filaments are allocated from the core contemplated.This effect is also illustrated by the shaded bands marked 149-151, and152-154, respectively, in FIGS. 14C and 14D.

Since the overall numbers of fibers and filaments present is generallynot increased by a mere allocation of filaments from core to scrimlayers, the reasons for this effect are not currently well understood.However, it was predicted that consumers of products made from thestructure, such as baby wipes, would prefer comparatively greateropacity, since comparatively greater opacity equates with comparativelyless translucency, making the wipe look more substantial and as if itbetter creates a physical barrier between the user's hand and soil (e.g.fecal matter) that the wipe is used to clean away from the baby's skin.

In another assessment, the seventeen variants were presented to a panelof human respondents, who were asked to evaluate the structure samplesand rate them according to the extent to which they subjectively deemedthem flexible. A subjective scoring system was used. Another regressionanalysis was applied to the data collected, and yielded a formula thatis reflected in FIGS. 14E and 14F. Generally, the formula predicts thatrelatively higher pulp content and relatively lower allocation ofmeltblown filaments to the scrim layers results in a relatively higherflexibility rating, and vice versa, as reflected in shaded bands155-157, and 158-160, respectively, in FIGS. 14E and 14F.

Consumer preferences concerning flexibility are complex and notcurrently thoroughly understood. Without intending to be bound bytheory, it is believed that some consumers may prefer a comparativelymore flexible structure, perceiving it to be, for example, more soft andluxurious, while others may prefer a comparatively stiffer structure,perceiving it to be, for example, more robust and substantial.

In still another assessment, the seventeen variants were presented tothe panel of human respondents, who were asked to evaluate the structuresamples and rate them according to their perceptions of surfaceroughness. A subjective scoring system was used. Another regressionanalysis was applied to the data collected, and yielded a formula thatis reflected in FIG. 14G. Generally, the formula predicts thatrelatively lower allocation of meltblown filaments to the scrim layersresults in a relatively higher surface roughness rating, and vice versa,as reflected by shaded bands 161-164 in FIG. 14G.

Consumer preferences concerning surface roughness are also somewhatcomplex and not currently thoroughly understood. Without intending to bebound by theory, it is believed that some consumers may prefer a morerough-feeling structure (e.g., more like a paper towel), perceiving itto be, for example, more effective at sweeping, capturing and removingsoil from skin, while others may prefer more smooth-feeling structure,perceiving it to be, for example, more gentle to skin and/or more softand luxurious.

Although they provide some guidance concerning how to maximizeparticular properties such as tensile strength and opacity, theassessments described above do not appear to provide any certainguidance, prediction or expectation as to how to select a combination ofweight percent pulp fiber content vs. meltblown filament content, and anallocation of meltblown filament content between the core layer and thescrim layers, that will be most pleasing to consumers of wet wipes suchas baby wipes.

Samples of the seventeen variants that had been converted to wet wipeswere presented to another panel of consumer respondents, who were askedto evaluate the wipes samples and rate them according to the extent towhich they would prefer to purchase them as consumers. A subjectivescoring system was used. Another regression analysis was applied to thedata collected, and yielded a formula that, surprisingly, showed littlecorrelation with the formulas for tensile strength and opacity. Therewas little correlation between the predicted most preferred highertensile strength, the predicted most preferred higher opacity, and themost preferred consumer preference, for structures with varyingallocations of meltblown polymer filaments to the scrim layers. Rather,as reflected by respective shaded bands 165-169 and 170-174 in FIGS. 14Hand 14I, the Consumer Preference Indication formula suggests that thestrongest consumer preference falls within a narrow band of allocationof meltblown polymer filaments to the outer scrim layers, from about 1.0percent by weight of the total fibrous web structure allocated to thescrim layers, to about 13 percent by weight of the total fibrous webstructure, of meltblown polymer filaments allocated to the scrim layers,for, e.g., a 60 gsm fibrous web structure (FIG. 14F). At allocations ofmeltblown filament content lower than about 1.0 percent by weight of thestructure to the scrim layers, and higher than about 13 percent,consumer preference falls off sharply, for reasons currently notthoroughly understood.

A model derived from the regression analysis enables a prediction ofconsumer preference from the ranges of the basis weights and proportionsof pulp fibers of the samples tested. From the analysis, it is preferredthat the Consumer Preference Indication for a fibrous nonwoven structurebe greater than 0.0, more preferably 1.0 or more, still more preferably1.75 or more, and still more preferably 2.25 or more, where Consumerpreference Indication is calculated according to the following equation:CPI=(BW×0.06232)−6.00192A−6.84371B−3.95686C+13.67992AB+7.12309BC+2,where

-   -   A=[(Weight fraction pulp content)−0.64167]/0.175;    -   B=(Weight fraction meltblown filaments in scrim layers)/0.175;    -   C=[(Weight fraction meltblown filaments in core        layer)−0.18333]/0.175; and    -   BW=basis weight of the fibrous web structure in gsm.

Thus, as one example, according to the model described above and thedescription herein, a fibrous web structure having a basis weight of 60gsm and the following composition will be a within the range of consumerpreference indicated by CPI as set forth above:

-   -   17.40 gsm meltblown polypropylene filaments in middle/core        layer;    -   39.00 gsm SSK pulp fibers in middle/core layer;    -   3.60 gsm meltblown polypropylene filaments in outer/scrim layers        together (approximately 1.8 gsm in each); and    -   bond area percentage about 6.2%.

From the values above, the example structure will have 65.0 percent byweight pulp fibers, 6.00 percent by weight meltblown polymer filamentsin the two scrim layers together, and 29.0 percent by weight meltbownpolymer filaments in the middle/core layer, and will have a CPI of2.4071 according to the above model, indicating a consumer-preferredstructure.

In contrast, if the above example is modified such that 3.00 gsm isadditionally allocated from the core layer to each scrim layer(allocating a total of 9.60 gsm to the scrim layers together, or 4.80gsm to each), the structure would have 16.0 percent by weight meltblownpolymer filaments in the two scrim layers, and 19.0 percent by weightmeltbown polymer filaments in the middle/core layer, and will have a CPIof about −0.1108, indicating a structure that is outside theconsumer-preferred range in which the CPI is greater than 0.

It may be recognized that a web formed of meltblown polymer filaments toa basis weight of 4.8 gsm or less, by itself, is extremely thin andsheer, and barely tactilely perceptible when held in the hands. Thisillustrates the surprising sensitivity of consumer preference toallocation of meltblown filaments to the scrim layers, according to themodel. It may be appreciated from the foregoing that consumerpreferences are often elusive to prediction and that more than routineexperimentation is necessary to discover them and then harmonize themwith manufacturer preferences for features such as material strength,manufacturing cost and efficiency. The above-described formula forachieving a CPI greater than 0, more preferably 1, still more preferably2, showed little correlation with the formulas that indicatemaximization of properties such as tensile strength, opacity, surfaceroughness and flexibility with respect to choosing a combination of pulpfiber content, meltblown filament content and allocation of meltblownfilaments between core and scrim layers.

Results of further consumer testing have suggested that extrapolationfrom the model above may yield ranges of consumer-preferred allocationsof meltblown filaments for higher and lower proportionate pulp contentstructures than the variants made, tested and shown and plotted in theternary plots of FIGS. 12-14I. This extrapolation is reflected by thedotted-line parallelogram 175 drawn on the ternary plot of FIG. 12.Extrapolation indicates a preferred weight percent pulp content of 60%to 90%, combined with a preferred meltblown filament weight percentcontent in the scrim layers (combined) of 1.0% to 13%.

Based on the foregoing, examples of a fibrous nonwoven structure arecontemplated having a combination of the following features:

-   -   Basis weight: 40 gsm to 100 gsm, more preferably 50 gsm to 90        gsm, more preferably 55 to 85 gsm, and still more preferably 60        gsm to 80 gsm, or alternatively, any combination of the lower        and upper values of the above ranges, e.g., 40-85 gsm, 40-80        gsm, etc.;    -   Composition: 60 to 90 percent by weight cellulose fibers,        preferably wood pulp fibers, and more preferably a blend of        softwood and hardwood fibers, and still more preferably a blend        of SSK fibers and hardwood fibers, for example, eucalyptus        fibers; and 10 to 40 percent by weight meltblown polymer        filaments, more preferably meltblown polyolefin filaments, and        still more preferably meltblown filaments formed predominately        of polypropylene; and        -   (a) From about 1.0 weight percent to about 13.0 weight            percent of the structure, of meltblown filaments in scrim            layers, or more preferably, from about 3 weight percent to            about 11 weight percent of the structure, of meltblown            filaments in scrim layers, still more preferably, from about            5 weight percent to about 9 weight percent of the structure,            of meltblown filaments in scrim layers, or alternatively,        -   (b) allocation of meltblown filaments between core layer(s)            and scrim layers such that the CPI according to the model            above is greater than 0, more preferably 1.0 or greater,            still more preferably 1.75 or greater, and even more            preferably 2.25 or greater,            -   where alternative (a) or (b) is combined with a basis                weight for at least one scrim layer of at least 0.1 gsm                and a combined basis weight that is equal to or less                than 13 weight percent of the structure; or                alternatively,        -   (c) the basis weight of a single scrim layer (i.e., on one            side of the structure) is kept within a range of from 0.1            gsm to less than 3.0 gsm.

In hindsight of this research and analysis it appears that consumerswill prefer a wet wipe cut from a fibrous web material having at leastsome of the total meltblown polymer fiber weight content allocated toscrim layers, but that that preference is very sensitive and falls offsharply when the allocation of meltblown filaments to the scrim layersstrays above or below a relatively narrow band, as suggested in FIGS.14H and 14I. Expressed differently, the benefits of scrim layers on afibrous web structure are believed to be best realized, from a consumerpreference perspective, when included, but kept to low basis weightswithin the ranges described herein.

The amount of meltblown polymer filaments allocated to the two scrimlayers may be divided approximately equally, or may be dividedunequally. For example, it may be desired that the two sides of thefibrous nonwoven structure have different feel or surfacecharacteristics, for example, that one side have a more rough orhigher-friction feel, and the other side have a more smooth or slick,lower-friction feel. To accomplish such difference, the scrim layer onone side may be imparted with a lower basis weight of, for example, from0.1 gsm to 1.4 gsm, or to 1.0 gsm, or even to 0.6 gsm. Correspondingly,the scrim layer on the other side may be imparted with a higher basisweight of, for example, from 0.6 gsm to 3.0 gsm, or from 0.8 gsm to 2.8gsm, or even from 1.0 gsm to 2.6 gsm. In order to provide the pulp fibercontainment benefit of a scrim layer, however, as noted above, it may bedesired that the basis weight of either scrim layer and preferably bothscrim layers be at least 0.1 gsm, more preferably at least 0.2 gsm, oreven more preferably at least 0.3 gsm. For example, for a fibrousnonwoven structure having a basis weight of, e.g., 60 gsm, this meansthat it may be desired that the weight percentage of either orpreferably both scrim layers be at least 0.17%, or 0.34% combined.

The basis weight of the fibrous web structure, the overall weightpercent pulp content vs. meltblown filament content, and the allocationof meltblown filaments between core layer(s) and scrim layers may beadjusted and regulated by design, adjustment and regulation of thespeeds and/or feed rates to components that introduce the materials inthe manufacturing line, including the components that separate and feedthe pulp fibers and entrain them in airstream(s), the banks of filamentspinnerets, the forming belt, etc.

The fibrous web structure and/or any product comprising such fibrous webstructure may be subjected to any post-processing operations such asembossing operations, printing operations, tuft-generating operations,thermal bonding operations, ultrasonic bonding operations, perforatingoperations, surface treatment operations such as application of lotions,silicones and/or other materials, folding, and mixtures thereof.

Non-limiting examples of suitable polypropylenes for making thefilaments are commercially available from Lyondell-Basell andExxon-Mobil.

Any hydrophobic or non-hydrophilic materials within the fibrous webstructure, such as polypropylene filaments, may be surface treatedand/or melt treated with a hydrophilic modifier. Non-limiting examplesof surface treating hydrophilic modifiers include surfactants, such asTriton X-100. Non-limiting examples of melt treating hydrophilicmodifiers that are added to the melt, such as the polypropylene melt,prior to spinning filaments, include hydrophilic modifying meltadditives such as VW351 and/or S-1416 commercially available fromPolyvel, Inc. and Irgasurf commercially available from Ciba. Thehydrophilic modifier may be associated with the hydrophobic ornon-hydrophilic material at any suitable level known in the art. In oneexample, the hydrophilic modifier is associated with the hydrophobic ornon-hydrophilic material at a level of less than about 20% and/or lessthan about 15% and/or less than about 10% and/or less than about 5%and/or less than about 3% to about 0% by dry weight of the hydrophobicor non-hydrophilic material.

The fibrous web structure may include optional additives, each, whenpresent, at individual levels of from about 0% and/or from about 0.01%and/or from about 0.1% and/or from about 1% and/or from about 2% toabout 95% and/or to about 80% and/or to about 50% and/or to about 30%and/or to about 20% by dry weight of the fibrous web structure.Non-limiting examples of optional additives include permanent wetstrength agents, temporary wet strength agents, dry strength agents suchas carboxymethylcellulose and/or starch, softening agents, lint reducingagents, opacity increasing agents, wetting agents, odor absorbingagents, perfumes, temperature indicating agents, color agents, dyes,osmotic materials, microbial growth detection agents, antibacterialagents and mixtures thereof.

In addition to wipes, the fibrous web structure described herein may beconverted to a sanitary tissue product or household cleaning productsuch as bath tissue or paper towels. It may be convolutedly wound abouta core to form a roll. It may be combined with one or more other fibrousweb structures as a layer to form a multi-layer product. In one example,a co-formed fibrous web structure may be convolutedly wound about a coreto form a roll of co-formed product. A roll product may also becoreless.

Wipe

The fibrous web structure, as described above, may be utilized to form awipe. “Wipe” is a general term to describe a sheet of material,typically cut from a non-woven web material, adapted for cleaning hardsurfaces, food, inanimate objects, toys and body parts. In particular,many currently available wipes (including baby wipes) are adapted foruse in cleaning of the perianal area of the body after defecation. Otherwipes may be available for cleaning the face or other body parts.Multiple wipes may be attached together by any suitable method to form amitt.

The material from which a wipe is made should be strong enough to resisttearing during normal use, yet still provide softness to the user'sskin, such as a child's tender skin. Additionally, the material shouldbe at least capable of retaining its form for the duration of the user'scleansing experience.

Wipes may be generally of sufficient dimension to allow for convenienthandling. Typically, the wipe may be cut and/or folded to suchdimensions as part of the manufacturing process. In some instances, thewipe may be cut into individual sheets so as to provide separate wipeswhich are often stacked, folded and interleaved in consumer packaging.In other embodiments, the wipes may be in a web form where the web hasbeen slit and folded to a predetermined width and provided with means(e.g., perforations) to allow individual wipes to be separated from theweb by a user. Wipes sheets divided by perforations may be gathered on aroll (in the manner of conventional dry bathroom tissue or papertowels).

Suitably, an individual wipe may have a length between about 100 mm andabout 250 mm and a width between about 140 mm and about 250 mm. In oneembodiment, the wipe may be about 200 mm long and about 180 mm wideand/or about 180 mm long and about 180 mm wide and/or about 170 mm longand about 180 mm wide and/or about 160 mm long and about 175 mm wide.The material of the wipe may generally be soft and flexible, potentiallyhaving a structured surface to enhance its cleaning performance.

In one example the surface of the fibrous web structure may besubstantially, macroscopically flat. In another example the surface ofthe fibrous web structure may optionally contain raised and/or loweredportions. These can be in the form of logos, indicia, trademarks,geometric patterns, images of the surfaces that the substrate made fromthe structure is intended to clean (i.e., infant's body, face, etc.).They may be randomly arranged on the surface of the fibrous webstructure or be in a repetitive pattern of some form.

In another example the fibrous web structure may be biodegradable. Forexample the fibrous web structure may be made from a biodegradablematerial such as a polyesteramide, or high wet strength cellulose.

In one example, the fibrous web structure is used to form apre-moistened wipe, such as a baby wipe. A plurality of thepre-moistened wipes may be stacked one on top of the other and may becontained in a container, such as a plastic tub or a film wrapper. Inone example, the stack of pre-moistened wipes (typically about 40 to 80wipes/stack) may exhibit a height of from about 50 to about 300 mmand/or from about 75 to about 125 mm. The pre-moistened wipes maycomprise a liquid composition, such as a lotion. The pre-moistened wipesmay be stored long term in a stack in a liquid impervious container orfilm pouch without all of the lotion draining from the top of the stackto the bottom of the stack.

In one example, the pre-moistened wipes are present in a stack ofpre-moistened wipes that exhibits a height of from about 50 to about 300mm and/or from about 75 to about 200 mm and/or from about 75 to about125 mm.

Wipes of the present invention may be saturation loaded with a liquidcomposition to form a pre-moistened wipe. The loading may occurindividually, or after the fibrous web structures or wipes are place ina stack, such as within a liquid impervious container or packet. In oneexample, the pre-moistened wipes may be saturation loaded with fromabout 1.5 g to about 6.0 g and/or from about 2.5 g to about 4.0 g ofliquid composition per gram of fibrous nonwoven structure.

In one example, the liquid composition comprises water or another liquidsolvent. Generally the liquid composition is of sufficiently lowviscosity to impregnate the entire structure of the fibrous webstructure. In another example, the liquid composition may be primarilypresent at the fibrous web structure surface and to a lesser extent inthe inner structure of the fibrous web structure. In a further example,the liquid composition is releasably carried by the fibrous webstructure, that is the liquid composition is carried on or in thefibrous web structure and is readily releasable from the fibrous webstructure by applying some force to the fibrous web structure, forexample by wiping a surface with the fibrous web structure.

Liquid compositions useful in the present invention may be, but are notnecessarily limited to, oil-in-water emulsions. In one example, theliquid composition may be at least 80% and/or at least 85% and/or atleast 90% and/or at least 95% by weight water.

When present on or in the fibrous web structure, the liquid compositionmay be present at a level of from about 10% to about 1000% of the basisweight of the fibrous web structure and/or from about 100% to about 700%of the basis weight of the fibrous web structure and/or from about 200%to about 500% and/or from about 200% to about 400% of the basis weightof the fibrous web structure.

The liquid composition may comprise an acid. Non-limiting examples ofacids that may be included in the liquid composition are adipic acid,tartaric acid, citric acid, maleic acid, malic acid, succinic acid,glycolic acid, glutaric acid, malonic acid, salicylic acid, gluconicacid, polymeric acids, phosphoric acid, carbonic acid, fumaric acid andphthalic acid and mixtures thereof. Suitable polymeric acids can includehomopolymers, copolymers and terpolymers, and may contain at least 30mole % carboxylic acid groups. Specific examples of suitable polymericacids useful herein include straight-chain poly(acrylic) acid and itscopolymers, both ionic and nonionic, (e.g., maleic-acrylic,sulfonic-acrylic, and styrene-acrylic copolymers), those cross-linkedpolyacrylic acids having a molecular weight of less than about 250,000,preferably less than about 100,000 poly (α-hydroxy) acids, poly(methacrylic) acid, and naturally occurring polymeric acids such ascarageenic acid, carboxy methyl cellulose, and alginic acid. In oneexample, the liquid composition comprises citric acid and/or citric acidderivatives.

The liquid composition may also contain salts of the acid or acids usedto lower the pH, or another weak base to impart buffering properties tothe fibrous web structure. The buffering response is due to theequilibrium which is set up between the free acid and its salt. Thisallows the fibrous web structure to maintain its overall pH despiteencountering a relatively high amount of bodily waste as would be foundpost urination or defecation in a baby or adult. In one embodiment theacid salt would be sodium citrate. The amount of sodium citrate presentin the lotion would be between 0.01 and 2.0%, alternatively 0.1 and1.25%, or alternatively 0.2 and 0.7% of the lotion.

In one example, the liquid composition does not contain any preservativecompounds.

In addition to the above ingredients, the liquid composition maycomprise additional ingredients. Non-limiting examples of additionalingredients that may be included in the liquid composition include: skinconditioning agents (emollients, humectants) including waxes such aspetrolatum, cholesterol and cholesterol derivatives; di- andtri-glycerides including sunflower oil and sesame oil; silicone oilssuch as dimethicone copolyol, caprylyl glycol; and acetoglycerides suchas lanolin and its derivatives; emulsifiers; stabilizers; surfactantsincluding anionic, amphoteric, cationic and nonionic surfactants;colorants; chelating agents including EDTA; sun screen agents;solubilizing agents; perfumes; opacifying agents; vitamins; viscositymodifiers such as xanthan gum; astringents; and external analgesics.

The liquid composition also may be formulated as described in any of,for example, U.S. Pat. Nos. 8,221,774 and 8,899,003; and U.S. patentapplication Ser. No. 11/717,928; 11/807,139; 12/105,654; 12/611,310;12/771,391; 12/976,180; 13/220,982; 13/752,639; 14/330,171; 14/493,469;14/602,692; and 62/057,297. An opacifying lotion formulation such asdescribed in, for example, U.S. patent application Ser. No. 13/220,982,may be particularly useful for imparting opacity to, or enhancingopacity of, a fibrous web structure, particularly one with a lower basisweight, e.g., from 40-80 gsm, 40-70 gsm, or even 40-60 gsm, having theeffect of interacting with the pulp fibers (including the relativelyfine hardwood pulp fibers, when included) in a synergistic way toincrease opacity of the structure and thereby enhance an appearance ofrobustness and barrier functionality of a wet wipe made from the fibrousnonwoven structure.

Wipes of the present invention may be placed in the interior of acontainer, which may be liquid impervious, such as a plastic tub or asealable packet, for storage and eventual sale to the consumer. Thewipes may be folded and stacked. The wipes of the present invention maybe folded in any of various known folding patterns, such as C-folding,Z-folding and quarter-folding. Use of a Z-fold pattern may enable afolded stack of wipes to be interleaved with overlapping portions.Alternatively, the wipes may include a continuous strip of materialwhich has perforations between each wipe and which may be arranged in astack or wound into a roll for dispensing, one after the other, from acontainer, which may be liquid impervious.

The fibrous web structure or wipes of the present invention may furtherinclude prints, which may provide aesthetic appeal. Non-limitingexamples of prints include figures, patterns, letters, pictures andcombinations thereof.

Method for Making a Co-Formed Fibrous Web Structure

A non-limiting example of a method for making a co-formed fibrous webstructure or a core layer thereof according to the present invention isschematically illustrated in FIG. 7A. The method illustrated in FIG. 7Acomprises the step of mixing a plurality of fibers 14 with a pluralityof filaments 12. In one example, the fibers 14 are wood pulp fibers,such as SSK fibers and/or eucalyptus fibers, and the filaments 12 arepolypropylene filaments. The fibers 14 may be combined with thefilaments 12, such as by being delivered to a stream of filaments 12from a hammermill 42 via a fiber spreader 44 to form a mixture offilaments 12 and fibers 14. The filaments 12 may be created bymeltblowing from a meltblowing spinneret 46. The mixture of fibers 14and filaments 12 are collected on a collection device, such as a formingbelt 48 to form a fibrous web structure 50. The collection device may bea patterned and/or molded belt that results in the fibrous web structureexhibiting a surface pattern, such as a non-random, repeating pattern ofmicroregions. The patterned and/or molded belt may have athree-dimensional pattern on it that is imparted to the fibrous webstructure 50 during the process. For example, a patterned belt 48, asshown in FIG. 8, may comprise a reinforcing structure, such as a fabric54, upon which a polymer resin 56 is molded or otherwise applied toreflect a three-dimensional pattern. The pattern may comprise acontinuous or semi-continuous network 58 of the polymer resin 56 withinwhich one or more discrete conduits 60 are arranged.

In another example schematically illustrated in FIG. 7B, a multilayerfibrous web structure 50 with outer scrim layers on both sides may bemade in a single-pass, direct-forming process, with no interveninggathering or storage of component layers, e.g., on a roll. “Directforming” means that each component layer of the structure following thefirst-formed layer is formed directly over the first layer or alater-formed layer, rather than being formed separately.

In a single-pass, direct forming process, a first meltblowing spinneret46 a may be used to spin a plurality of first meltblown filaments 12 athat may be accumulated on a moving forming surface, such as the surfaceof a moving forming belt 48, to form a first scrim layer.

Downstream in the process, a configuration of co-forming equipment thatmay include co-form meltblowing spinneret 46 b, a fiber spreader 44, anda mixing box such as co-form box 74, may be arranged and configured todeliver meltblown filaments and air-entrained pulp fibers, respectivelyto the mixing box such as co-form box 74. In the co-form box thefilaments and fibers may be blended, entangled and entrained in an airstream to form a co-form stream 14 a, which may then be directed to amoving forming surface (such as belt 48) to accumulate and form aco-form layer. In the example illustrated in FIG. 7B, the co-form layermay be accumulated and formed directly over and overlying the firstscrim layer. In some examples, a plurality of configurations ofco-forming equipment may be arranged in succession to deliver aplurality of co-form streams 14 a in succession to build up thethickness and basis weight of the co-form layer accumulation. This mayenable greater manufacturing line speed than use of only a singleconfiguration of co-forming equipment, and may also provide a mechanismfor increasing or regulating basis weight of the co-form layer when theoperating speed of belt 48 is governed by other concerns, e.g., thedesired basis weight of the scrim layer(s).

Further downstream in the process, a second meltblowing spinneret 46 bmay be used to spin a plurality of second meltblown filaments 12 b thatmay be accumulated on a moving forming surface, such as the surface ofmoving forming belt 48, to form a second scrim layer. In the exampleillustrated in FIG. 7B (schematically illustrating a single-pass, directforming process), the second scrim layer may be accumulated and formeddirectly over and overlying the previously-formed co-form layer.

The fiber spreader(s) 44 may be configured, and may comprise equipmentincluding an educator, as described in, for example, U.S. Patent App.Ser. No. 62/094,087. The co-form box may be configured as described in,for example, U.S. Patent App. Ser. No. 62/094,089.

As reflected in FIGS. 7A and 7B, the process for forming the fibrous webstructure may be a direct forming process in which the layers of thestructure are formed sequentially by depositing components of overlyinglayers directly onto previously deposited components of underlyinglayers—as contrasted with a process in which one or more of the scrimand/or co-form layers are formed separately and, e.g., conveyed as afully-formed layer to the fibrous web structure forming process. Adirect forming process may be preferred for purposes herein in whichcomparatively low basis weight scrim layers formed of meltblownfilaments are contemplated, as such layers may in ordinary circumstancesbe too weak (i.e., have insufficient machine-direction tensile strength)to be self-supporting and rolled/unrolled, or otherwise conveyed,separately. In addition, it is believed that a direct forming processprovides another benefit. Without intending to be bound by theory, it isbelieved that formation of a layer by depositing fibers and/or filamentsdirectly onto and over another previously-formed layer results incomparatively greater intermingling and/or entangling of fibers and/orfilaments at the interface between the layers, providing a more unitizedmultilayer fibrous web structure in which the layers are less likely toseparate, e.g., in downstream processes or in consumer use of an endproduct made from the fibrous web structure. A single-pass, directforming process may be more efficient by enabling greater manufacturingspeeds, and less use of plant space and resources.

Referring to FIGS. 9A and 9B, the filament components of the fibrous webstructure may be made using a meltblowing spinneret 46 comprising aplurality of filament nozzles 63 that may be arranged in rows, fromwhich filaments are spun. Melted polymer may be extruded under pressurethrough the nozzles 63, whereby it is forced through the nozzles to exitas polymer streams from melt outlets 62. The spinneret may includeannular attenuating fluid (e.g., air) outlets 64 about the nozzles, fromwhich heated, pressurized gaseous fluid (e.g. air) may be caused to exitthe spinnerets at high speed and flow along the lengths of the nozzlesand past their ends, as the polymer streams exit the melt outlets 62.The nozzles or spinneret may include features to affect direction and/orfeatures of the fluid streams (such as to induce or increase turbulence)about the exiting melted polymer streams, such as flutes 65. The hotgaseous fluid (e.g., air) flowing at high speed past the ends of thenozzles will entrain the polymer streams and thereby lengthen andattenuate them, to create fine filaments.

As shown in FIGS. 9A and 9B, in some examples, the nozzle may bepositioned within an attenuating fluid outlet. The melt outlet 62 may beconcentrically or substantially concentrically positioned within theattenuating fluid outlet 64 such as is suggested in FIGS. 9A and 9B.

Following attenuation, the filaments may be air quenched with coolingair. The filaments forming the scrim layers (e.g., those from spinnerets46 a and 46 c, as shown in the example of FIG. 7B) may be air-quenched,or mist quenched with a mixture of cooling air and water droplets.Mist-quenching is an efficient way to increase the rate of cooling ofthe scrim filaments and impart comparatively greater tensile strengthand elongation capability to them. The water droplets evaporate quickly,removing heat, when they contact the combination of hot air and hotpolymer streams, such that a subsequent drying step is not necessary.Chilling the cooling air (e.g. via passing it over a heat exchangerthrough which coolant fluid circulates, such as an evaporator) is analternative method of achieving more rapid cooling of the filaments, butis less effective and energy-efficient than mist-quenching. However,mist-quenching may in some circumstances not be deemed suitable for thefilaments from the co-form meltblowing spinneret, as this may causewater to be introduced into the co-forming process, causingcomplications that may include clumping of pulp fibers, or thenecessity, complication and expense of an additional drying step.

Following quenching the filaments may be directed directly at a movingcollecting and/or forming surface such as a forming belt 48 (e.g., asshown in FIGS. 7A, 7B) to form scrim layer(s), or alternatively, may bedirected into a co-form box 47 (e.g., as shown in FIG. 7B) to form aco-form layer.

After the layers have been formed or deposited on the collectingsurface, such as a belt 48, they may be calendered, for example, whilethe deposited layers of filaments and fibers are still on the collectiondevice, or downstream thereof. In one example as shown in FIG. 7B, theaccumulated first scrim layer, co-form layer, and second scrim layer maybe passed together into the nip 49 c between a pair of calender rollers49 a, 49 b. One or both of the calender rollers may have etched,machined or otherwise formed on its cylindrical surface a pattern ofbonding protrusions having functional and/or decorative features andappearance; one possible example (among a practically unlimited numberof variants) is shown in FIG. 10. One or both calender rollers 49 a, 49b may be heated, or a source of heat energy (such as, for example,ultrasound energy) may be supplied at the nip, and the rollers may beconfigured to exert a controlled amount of pressure on the layers in thenip. Thus, as the accumulated first scrim layer, co-form layer, andsecond scrim layer pass through the nip, the fibers and filamentsthereof are consolidated in the z-direction and the polymer filamentsare heated and compressed together beneath the bonding protrusions ofthe roller bearing the same, and may be at least partially fused to formthermal bonds, extending through the structure in the z-direction andbonding the respective scrim layers 38, 40 to the structure at bonds 70,as may be appreciated from FIG. 6C. In order to most effectively formsuch thermal bonds, it may be desired that the polymer(s) or blend(s)thereof forming the filaments of the respective scrim layers 38, 40 andthe filaments in the co-form layer(s) 36 be of like chemistry. Asreflected in FIG. 7B, formation of the first scrim layer, core layer(s)and second scrim layer, and consolidation and thermal bonding of thelayers to form a bonded fibrous web structure, may be performed in asingle pass, direct forming process, i.e., with no interveningconveying, gathering or storing of layers occurring between theformation thereof, and formation of the completed fibrous web structure.This may be process- and cost-efficient, and also removes the need for aminimum basis weight for scrim layers sufficient to make themself-supporting for purposes of conveying separately and/or gathering ona roll. In turn, this enables inclusion of relatively low basis weightscrim layers as contemplated herein, in the fibrous web structure.

The surface area occupied by the bonds 70 relative to the total surfacearea of the fibrous web structure may be expressed as bond areapercentage, and is calculated as the total surface area occupied by thebonds 70, divided by the overall surface area of a side of the fibrousweb structure 50 on which the bonds appear, ×100%. Bond area percentageon a fibrous web structure approximately reflects bonding areapercentage of the raised (bonding) surfaces of the bonding protrusionson a calender bonding roller, divided by the total surface area of thecircumscribing cylindrical shape of the portion of the calender bondingroller that contacts the web structure in the nip. Bond area percentagemay be increased or decreased by altering the design of the pattern ofbonding protrusions on the calendar bonding roller. Bonding protrusionshaving larger bonding surface area and/or more dense spacing impartcomparatively greater bond area percentage to the web structure, whilebonding protrusions having smaller bonding surface area and/or lessdense spacing impart comparatively lesser bond area percentage to theweb structure. Generally, it is believed that, within the practicaloperating ranges contemplated herein, greater bond area percentage mayimpart comparatively greater machine and cross direction tensilestrength, but also comparatively greater stiffness, in the webstructure. Conversely, comparatively lesser bond area percentage mayimpart comparatively less machine and cross direction tensile strength,and comparatively less stiffness (i.e., greater flexibility), in the webstructure. For purposes of the present disclosure and of striking thebest balance between strength and consumer preferences in the fibrousweb structure, it may be desired that thermal bond area percentage be ina range of from 2% to 12%, more preferably from 3% to 10%, even morepreferably from 4% to 8%, and still more preferably from 5% to 7%.

In addition, the fibrous web structure 50 may be subjected to otherpost-processing operations such as embossing, tuft-generatingoperations, moisture-imparting operations, and surface treatingoperations to form the finished fibrous web structure. One example of asurface treating operation that the fibrous web structure may besubjected to is the surface application of an elastomeric binder, suchas ethylene vinyl acetate (EVA), latexes, and other elastomeric binders.Such an elastomeric binder may aid in reducing the lint created from thefibrous web structure during use by consumers. The elastomeric bindermay be applied to one or more surfaces of the fibrous web structure in apattern, especially a non-random, repeating pattern of microregions, orin a manner that covers or substantially covers the entire surface(s) ofthe fibrous web structure.

In one example, the fibrous web structure 50 and/or the finished fibrousweb structure may be combined with one or more other fibrous webstructures. For example, another fibrous web structure, such as afilament-containing fibrous web structure, such as a polypropylenefilament fibrous web structure may be associated with a surface of thefibrous web structure 50 and/or the finished fibrous web structure. Thepolypropylene filament fibrous web structure may be formed bymeltblowing polypropylene filaments (filaments that comprise a secondpolymer that may be the same or different from the polymer of thefilaments in the fibrous web structure 50) onto a surface of the fibrousweb structure 50 and/or finished fibrous web structure. In anotherexample, the polypropylene filament fibrous web structure may be formedby meltblowing filaments comprising a second polymer that may be thesame or different from the polymer of the filaments in the fibrous webstructure 50 onto a collection device to form the polypropylene filamentfibrous web structure. The polypropylene filament fibrous web structuremay then be combined with the fibrous web structure 50 or the finishedfibrous web structure to make a two-layer fibrous webstructure—three-layer if the fibrous web structure 50 or the finishedfibrous web structure is positioned between two layers of thepolypropylene filament web structure may be thermally bonded to thefibrous web structure 50 or the finished fibrous web structure via athermal bonding operation.

In yet another example, the fibrous web structure 50 and/or finishedfibrous web structure may be combined with a filament-containing fibrousweb structure such that the filament-containing fibrous web structure,such as a polysaccharide filament fibrous web structure, such as astarch filament fibrous web structure, is positioned between two fibrousweb structures 50 or two finished fibrous web structures like that shownin FIG. 6A for example.

In one example, the method for making a fibrous web structure comprisesthe step of combining a plurality of filaments and optionally, aplurality of fibers to form a fibrous web structure that exhibits theproperties of the fibrous web structures described herein. In oneexample, the filaments comprise thermoplastic filaments. In one example,the filaments comprise polypropylene filaments. In still anotherexample, the filaments comprise natural polymer filaments. The methodmay further comprise subjecting the fibrous web structure to one or moreprocessing operations, such as calendaring the fibrous web structure. Inyet another example, the method further comprises the step of depositingthe filaments onto a patterned belt that creates a non-random, repeatingpattern of micro regions.

In still another example, two layers of fibrous web structure 50comprising a non-random, repeating pattern of microregions may beassociated with one another such that protruding microregions, such aspillows, face inward into the two-layer fibrous web structure formed.

The process for making a fibrous web structure 50 may be close coupled(where the fibrous web structure is convolutedly wound into a roll priorto proceeding to a converting operation) or directly coupled (where thefibrous web structure is not convolutedly wound into a roll prior toproceeding to a converting operation) with a converting operation toemboss, print, deform, surface treat, thermal bond, cut, stack or otherpost-forming operation known to those in the art. For purposes of thepresent invention, direct coupling means that the fibrous web structure50 can proceed directly into a converting operation rather than, forexample, being convolutedly wound into a roll and then unwound toproceed through a converting operation.

In one example, the fibrous web structure is embossed, cut into sheets,and collected in stacks of fibrous web structures.

A process according the present disclosure may include preparingindividual rolls and/or sheets and/or stacks of sheets of fibrous webstructure and/or sanitary tissue product comprising such fibrous webstructure(s) that are suitable for consumer use.

Non-Limiting Examples of Combinations Contemplated

The following non-limiting examples of combinations within thisdescription are contemplated:

1. A fibrous web structure comprising:

-   -   from 10 percent by weight to 40 percent by weight, more        preferably from 15 percent by weight to 35 percent by weight,        and even more preferably from 20 percent by weight to 30 percent        by weight meltspun polymer filaments; and    -   from 60 percent by weight to 90 percent by weight cellulose pulp        fibers, more preferably from 65 percent by weight to 85 percent        by weight cellulose pulp fibers, and still more preferably from        70 percent by weight to 80 percent by weight cellulose pulp        fibers,

wherein the fibrous web structure has first and second outer scrimlayers formed of a first portion of said meltspun polymer filaments, andan inner core layer formed of said pulp fibers intermixed with a secondportion of said meltspun polymer filaments, the fibrous web structurehaving a Consumer Preference Indication greater than 0, more preferablyequal to or greater than 1.0, more preferably equal to or greater than1.75, and still more preferably equal to or greater than 2.25, saidfirst portion forming from 1 percent to 13 percent of the weight of thefibrous web structure.

2. A fibrous web structure comprising:

-   -   from 10 percent by weight to 40 percent by weight, more        preferably from 15 percent by weight to 35 percent by weight,        and even more preferably from 20 percent by weight to 30 percent        by weight meltspun polymer filaments; and    -   from 60 percent by weight to 90 percent by weight cellulose pulp        fibers, more preferably from 65 percent by weight to 85 percent        by weight cellulose pulp fibers, and still more preferably from        70 percent by weight to 80 percent by weight cellulose pulp        fibers,

wherein the fibrous web structure has first and second outer scrimlayers formed of a first portion of said meltspun polymer filaments, andan inner core layer formed of said pulp fibers intermixed with a secondportion of said meltspun polymer filaments, the first and secondportions of said meltspun polymer filaments together comprising all ofsaid meltspun polymer filaments, said first portion constituting from 1percent to 13 percent of the weight of the fibrous web structure, morepreferably from 3 percent to 11 percent of the weight of the fibrous webstructure, and even more preferably from 5 percent to 9 percent of theweight of the fibrous web structure.

3. A fibrous web structure comprising:

-   -   from 10 percent by weight to 40 percent by weight, more        preferably from 15 percent by weight to 35 percent by weight,        and even more preferably from 20 percent by weight to 30 percent        by weight meltspun polymer filaments; and    -   from 60 percent by weight to 90 percent by weight cellulose pulp        fibers, more preferably from 65 percent by weight to 85 percent        by weight cellulose pulp fibers, and still more preferably from        70 percent by weight to 80 percent by weight cellulose pulp        fibers,

wherein the fibrous web structure has first and second outer scrimlayers formed of a first portion of said meltspun polymer filaments, andan inner core layer formed of said pulp fibers intermixed with a secondportion of said meltspun polymer filaments, the first and secondportions of said meltspun polymer filaments together comprising all ofsaid meltspun polymer filaments, at least one of the scrim layers havinga basis weight of from 0.1 gsm to less than 3.0 gsm, more preferablyfrom 0.3 gsm to 2.8 gsm, and still more preferably from 0.5 gsm to 2.6gsm.

4. The fibrous web structure of any of the preceding examples whereinthe cellulose pulp fibers comprise wood pulp fibers.

5. The fibrous web structure of any of the preceding examples whereinthe polymer filaments comprise polyolefin, preferably predominatelypolyolefin.

6. The fibrous web structure of example 5 wherein the polyolefincomprises polypropylene, preferably predominately polypropylene.

7. The fibrous web structure of any of the preceding examples whereinthe fibrous web structure bears an impressed pattern of thermal bonds atwhich meltspun polymer filaments of each of the first and second outerscrim layers are deformed and fused.

8. The fibrous web structure of example 7 wherein the thermal bondsoccupy from 2 percent to 12 percent, more preferably from 3 percent to10 percent, and even more preferably from 4 percent to 8 percent, of thesurface area of the fibrous web structure on one side thereof.

9. The fibrous web structure of any of the preceding examples whereinthe meltspun polymer filaments forming the first and second outer scrimlayers comprise polymers of like chemistry.

10. The fibrous web structure of any of the preceding examples whereinthe cellulose pulp fibers comprise softwood pulp fibers, preferably SSKfibers.

11. The fibrous web structure of any of the preceding examples whereinthe cellulose pulp fibers comprise hardwood pulp fibers, preferablyaspen, birch or eucalyptus fibers.

12. The fibrous web structure of any of the preceding examples whereinat least some of the first portion of the meltspun polymer filamentshave been mist-quenched.

13. The fibrous web structure of any of the preceding examples whereinthe first and second outer scrim layers each has a basis weight equal toor greater than 0.1 gsm.

14. The fibrous web structure of any of the preceding examples whereinthe first and second outer scrim layers each has a basis weight lessthan 3.0 gsm, more preferably 2.8 gsm, and still more preferably 2.6gsm.

15. The fibrous web structure of any of the preceding examples whereinat least the first portion of said meltspun polymer filaments comprises,and more preferably the first and second portions of said meltspunpolymer filaments comprise, meltblown filaments.

16. A wet wipe comprising the fibrous web structure of any of thepreceding examples wetted with a liquid composition.

Non-Limiting Example of Process for Making a Fibrous Web Structure ofthe Present Invention

The following example was manufactured on a pilot line in a two-pass,direct forming process as follows:

Co-Formed Core Layer

A 21%:27.5%47.5%:4% blend, respectively, of PH835 polypropylene(LyondellBasell, London, UK):Metocene MF650W polypropylene(LyondellBasell, London, UK):Metocene MF650X (LyondellBasell, London,UK):White 412951 (Ampacet Corporation, Tarrytown, N.Y.) whiteningagent/opacifier is dry blended, to form a melt blend. The melt blend isheated to about 400° F.-405° F. through a melt extruder. A 15.5 inchwide Biax 12 row spinnerette with 192 nozzles per cross-direction inch,commercially available from Biax Fiberfilm Corporation, is utilized. 40nozzles per cross-direction inch of the 192 nozzles have a 0.018 inchinside diameter melt outlet hole while the remaining nozzles areplugged, i.e., there is no opening in the nozzle. Approximately 0.18grams per (open) hole per minute (ghm) of the melt blend is extrudedfrom the open nozzles to form meltblown filaments from the melt blend.

Approximately 415 SCFM of compressed air is heated such that the air hasa temperature of about 395° F. at the spinnerette. Approximately 420g/minute of Golden Isle (from Georgia Pacific) 4825 semi-treated SSKpulp (Georgia-Pacific, Atlanta, Ga.) is defibrated through a hammermillto form SSK wood pulp fibers. Approximately 2100 SCFM Air at atemperature of about 80° F. and about 75% relative humidity (RH) isdrawn into the hammermill. The pulp is conveyed as described in U.S.Pat. App. No. 62/170,176 using a motive air mass flow of approximately1200 SCFM via two fiber spreaders. The solid additive spreaders turnsthe pulp fibers and distributes the pulp fibers in the cross-directionsuch that the pulp fibers are injected into the stream of meltblownfilaments at a 45° angle through two 4 inch×15 inch cross-direction (CD)slots. The pulp conveying ductwork and geometry are as described in U.S.Pat. App. Ser. No. 62/170,169 and 62/170,172. A forming box surroundsthe area where the meltblown filaments and pulp fibers are commingled.This forming box is designed to reduce the amount of air allowed toenter or escape from this commingling area. The forming box is asdescribed in U.S. Pat. App. Ser. No. 62/170,179. A forming vacuum pullsair through a moving collection surface, such as a non-patterned formingbelt or through-air-drying fabric, thus collecting and accumulating thecommingled meltblown filaments and pulp fibers to form a fibrousstructure batt. An example of such a fabric is Albany InternationalElectrotech F541-28I. The forming vacuum level is adjusted to preventexcessive air from escaping from the forming box. The fibrous structurebatt formed by this process comprises about 78% by dry fibrous structureweight of pulp and about 22% by dry fibrous structure weight ofmeltblown filaments. The line speed is adjusted (in the present example,to approximately 69 feet/min.) to accumulate the fiber/filament blend toreach the desired basis weight. The batt is then gathered on a storageroll.

First Scrim Layer

-   -   Polymer resin blend: 21%: 27.5%: 47.5%: 4% blend, respectively,        of PH835 polypropylene (LyondellBasell, London, UK):Metocene        MF650W polypropylene (LyondellBasell, London, UK):Metocene        MF650X (LyondellBasell, London, UK):White 412951 whitening        agent/opacifier (Ampacet Corporation, Tarrytown, N.Y.).    -   The resin blend is heated to approximately 400° F.-405° F. in a        melt extruder.    -   The melt extruder is used to feed the heated resin blend to a        15.5 inch wide Biax 12 row spinneret with 192 holes per        cross-direction inch (Biax Fiberfilm Corporation, Greenville,        Wis.) having 8 holes of the 192 holes per cross-direction inch        with a 0.018 inch inside diameter melt outlet hole while the        remaining nozzles are plugged.    -   The resin blend throughput in the spinneret is 0.18 grams per        (open) hole per minute (ghm), i.e., 22.32 grams resin/minute        through the spinneret.    -   Compressed attenuating air is supplied to the spinneret at a        rate of 426 SCFM, heated such that it is at a temperature of        395° F. at the spinneret.    -   The attenuated filaments are water mist quenched using 2 misting        nozzles, one on each broad side of the filament stream, each        supplied with air at 35 psig and sufficient water supply for a        flow rate of 2.5 gallons/hour.    -   Following mist quenching, the filaments are directed to a first        foraminous belt supplied with vacuum, operating horizontally and        carrying the previously-formed coformed core layer (unwound from        its storage roll) and controlled to move at a machine direction        speed of approximately 86 feet/minute; the filaments are        accumulated over the core layer on a first side thereof to a        basis weight of approximately 2 gsm.        Second Scrim Layer    -   A second scrim layer is formed by producing meltblown filaments        in the same manner as for the first scrim layer as described        above.    -   The previously-made core layer and overlying first scrim layer        are released from the first foraminous belt, turned 90 degrees        on a roller, and passed to a second foraminous belt operating        vertically (also supplied with vacuum and moving at 92        feet/minute), to carry the core layer and first scrim layer,        with the first scrim layer in facing contact with the second        foraminous belt.    -   The filaments are directed toward the second foraminous belt and        the core layer, to directly form a second scrim layer overlying        the core layer, on a second side of the core layer.        Bonding    -   Following assembly of the three layers components of the fibrous        web structure as described above, they are conveyed to the nip        between a pair of calendar bonding rollers, adjusted to exert an        amount of pressure on the batt in the nip suitable to form        well-defined bonds without excessive material deformation        beneath or about the bonding protrusions.    -   One bonding roller, which is heated to 250° F. at its surface,        has pattern of bonding protrusions machined thereon in the        pattern reflected in FIG. 10, and having a bonding area of 6.2        percent.    -   As they pass through the nip, the layers are consolidated in the        z-direction and thermally bonded in the pattern to form a        thermally bonded fibrous web structure.

The dimensions and values disclosed herein are not to be understood asbeing strictly limited to the exact numerical values recited. Instead,unless otherwise specified, each such dimension is intended to mean boththe recited value and a functionally equivalent range surrounding thatvalue. For example, a dimension disclosed as “40 mm” is intended to mean“about 40 mm.”

All documents cited in the Background and Detailed Description areincorporated herein by reference to the extent not inconsistent with thespecific disclosure herein; but the citation of any document is not tobe construed as an admission that it is prior art with respect to thepresent invention. To the extent that any meaning or definition of aterm in this document conflicts with any meaning or definition of thesame term in a document incorporated by reference, the meaning ordefinition assigned to that term in this document shall govern.

While particular embodiments of the present invention have beenillustrated and described, it would be obvious to those skilled in theart that various other changes and modifications can be made withoutdeparting from the spirit and scope of the invention. It is thereforeintended to cover in the appended claims all such changes andmodifications that are within the scope of this invention.

What is claimed is:
 1. A container comprising: a stack of pre-moistenedwet wipes, wherein the stack has a height from about 50 mm to about 300mm, and wherein a majority of the pre-moistened wet wipes eachcomprises: a fibrous web structure comprising: from 10 percent by weightto 40 percent by weight meltspun polymer filaments; and from 60 percentby weight to 90 percent by weight cellulose pulp fibers; wherein thefibrous web structure has first and second outer scrim layers formed ofa first portion of the meltspun polymer filaments, and an inner corelayer formed of the pulp fibers intermixed with a second portion of themeltspun polymer filaments, at least one of the scrim layers having abasis weight of from 0.1 gsm to less than 3.0 gsm; wherein the fibrousweb structure bears an impressed pattern of thermal bonds at whichmeltspun polymer filaments of each of the first and second outer scrimlayers are deformed and fused; wherein the thermal bonds occupy from 2percent to 12 percent of the surface area of the fibrous web structureon one side thereof; and wherein from about 1.0 percent by weight of thefibrous web structure to about 13 percent by weight of the fibrous webstructure of the meltblown filaments are allocated to the scrim layers.2. The container of claim 1, wherein the majority of the pre-moistenedwet wipes each have a Consumer Preference Indication greater than
 0. 3.The container of claim 1, wherein the cellulose pulp fibers comprisewood pulp fibers.
 4. The container of claim 1, wherein the polymerfilaments comprise predominately polyolefin.
 5. The container of claim4, wherein the polyolefin comprises predominately polypropylene.
 6. Thecontainer of claim 1, wherein the meltspun polymer filaments forming thefirst and second outer scrim layers comprise polymers of like chemistry.7. The container of claim 1, wherein the cellulose pulp fibers comprisesoftwood pulp fibers.
 8. The container of claim 1, wherein the cellulosepulp fibers comprise hardwood pulp fibers.
 9. The container of claim 1,wherein at least some of the first portion of the meltspun polymerfilaments have been mist-quenched.
 10. The container of claim 1, whereinthe first and second outer scrim layers each has a basis weight equal toor greater than 0.1 gsm.
 11. The container of claim 10, wherein thefirst and second outer scrim layers each has a basis weight less than3.0 gsm.
 12. The container of claim 1, wherein at least the firstportion of the meltspun polymer filaments comprises meltblown filaments.13. The container of claim 1, wherein the container comprises a plastictub.
 14. The container of claim 1, wherein the container comprises afilm wrapper.
 15. The container of claim 1, wherein the majority of thepre-moistened wet wipes each comprises: a lotion; and water.
 16. Acontainer comprising: a stack of pre-moistened wet wipes, wherein thestack has a height from about 75 mm to about 200 mm, and wherein amajority of the pre-moistened wet wipes each comprises: a fibrous webstructure comprising: from 10 percent by weight to 40 percent by weightmeltspun polymer filaments; from 60 percent by weight to 90 percent byweight cellulose pulp fibers; wherein the fibrous web structure hasfirst and second outer scrim layers formed of a first portion of themeltspun polymer filaments, and an inner core layer formed of the pulpfibers intermixed with a second portion of the meltspun polymerfilaments, at least one of the scrim layers having a basis weight offrom 0.1 gsm to less than 3.0 gsm; and a liquid composition wherein fromabout 1.0 percent by weight of the fibrous web structure to about 13percent by weight of the fibrous web structure of the meltblownfilaments are allocated to the scrim layers.
 17. A container comprising:a stack of pre-moistened baby wipes, wherein the stack has a height fromabout 50 mm to about 300 mm, and wherein a majority of the pre-moistenedbaby wipes each comprises: a fibrous web structure comprising: from 10percent by weight to 40 percent by weight meltspun polymer filaments;from 60 percent by weight to 90 percent by weight cellulose pulp fibers;wherein the fibrous web structure has first and second outer scrimlayers formed of a first portion of the meltspun polymer filaments, andan inner core layer formed of the pulp fibers intermixed with a secondportion of the meltspun polymer filaments, at least one of the scrimlayers having a basis weight of from 0.1 gsm to less than 3.0 gsm; alotion; and water wherein from about 1.0 percent by weight of thefibrous web structure to about 13 percent by weight of the fibrous webstructure of the meltblown filaments are allocated to the scrim layers.18. The container of claim 17, wherein the container comprises a plastictub or a film wrapper.